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R3 H C O C O R2 H NH R4 R1 R3 HCOCO R2 Products HH N R4 R1 Amino acid General acid form General base form residues (proton donor) (proton acceptor) R COOH H R NH H R SH R C CH R COO R NH2 R S R C CH Glu, Asp Lys, Arg Cys His Ser Tyr R OH R O HN N CC HN NH HH R OH R O FIGURE 68 How a catalyst circumvents unfavorable charge devel- opment during cleavage of an amide.

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VersatilityofGlycolysisandTCACycle:Manypathwaysof metabolism are bidirectional, or amphibolic, pathways that can be adapted to serving several functions.


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